Thermoelectriceffect : the phenomena of production of current in thermocouple due to variation of heat is called thermoelectric effect .
It is classified into three different effects
- Seebeck effect
- Peltier effect
- Thomson effect
Seebeck effect: the phenomena of production of current in thermocouple due to temperature difference between two junction of thermocouple called seebeck effect.
produced EMF depend upon separation between metals , nature of metal and temperature difference of junction.
Cause of seebeck effect:
- Potential difference
- Different electron density
- Temperature difference create net potential difference which creating thermocouple EMF
\[Qn= \frac{ Q_{i}+ Q_{c}}{2}\]
Peltier effect : the phenomena of evaluation observation of heat at junction of thermocouple when current is made to pass through it is called peltier effect.
- Heat is evolved or absorbed
heat or cooling of function is determined by direction of current
Current flow through fe to Cu . heat will released Cu to Fe. it will absorbed at cold junction. This effect is reverse of seebuck effective.Cause of peltier effectcurrent
- Electron density increase at junction
- Electric field due to applied voltage
Heat absorb or release is directly proportional to current and temperature.
i.e. \[Q\ \alpha\ IT \rightarrow or \ Q =\pi IT\]
\[\Rightarrow \ \pi=\frac{Q}{It} \ or \frac{Q}{\frac{q}{t}t}\]
Cancling t
\[ units : JC^{-1}\]
Thomson effect: phenomena of evaluation or observation of heat along the length of an equally weighted conductor is called Thomson effect.
Cause of Thomson effect
- electron density gradient developed along length of conductor due to unequal heating of conductor.
Thomson coefficient: heat absorbed or evolved a long length of conductor/unit current/unit time, when and of conductor are maintained at unit temperature difference
\[Q\ \alpha \ I \rightarrow \ Q \ \alpha \ Itdt\Rightarrow \ \ Q=\partial Itdt \\\\ \partial=\frac{Q}{Itdt}=\frac{Q}{\frac{q}{t}tdt}=\frac{Q}{qdt}\]
\[ units: JA^{-1}S^{-1}k^{-1}\]
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